Substituted Methoxybenzene derivatives: C8H9NO4, C9H11NO5 and C13H18O4

Fun, H.-K., and Chinnakali, K., and Sivakumar, K., and Sam, T.-W., and How, Siew Eng (1997) Substituted Methoxybenzene derivatives: C8H9NO4, C9H11NO5 and C13H18O4. Acta Crystallographica, Section C: Crystal Structure Communications. pp. 1859-1862.

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Abstract

The structures of three methoxybenzenes, namely 1,2-dimethoxy-4-nitrobenzene, C8H9NO4, (I), 1,2,3-trimethoxy-5-nitrobenzene, C9H11NO5, (II), and 1-(2,4,5-trimethoxyphenyl)-1-butanone, C13H18O4, (III), are reported. Molecules of (I) and (III) are planar, but one of the three methoxy groups of (II) is twisted out of the phenyl ring plane as a result of steric hindrance. In all three solids, the molecules are linked to form centrosymmetrically hydrogen-bonded dimers; they are packed in parallel layers in (I) and (II), but in zigzag layers in (III).

Item Type: Article
Uncontrolled Keywords: Centrosymmetrically hydrogen-bonded dimers , methoxybenzenes
Subjects: Q Science > QD Chemistry
Divisions: FACULTY > Faculty of Science and Natural Resources
Depositing User: Noraini
Date Deposited: 28 Feb 2018 06:32
Last Modified: 28 Feb 2018 06:32
URI: http://eprints.ums.edu.my/id/eprint/18935

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