Bio-waste corn-cob cellulose supported poly(hydroxamic acid) copper complex for Huisgen reaction: Waste to wealth approach

Bablu Hira Mandal, and Md. Lutfor Rahman, and Mashitah Mohd Yusoff, and Kwok, Feng Chong and Shaheen M. Sarkar, (2016) Bio-waste corn-cob cellulose supported poly(hydroxamic acid) copper complex for Huisgen reaction: Waste to wealth approach. Carbohydrate Polymers, 156. pp. 175-181. ISSN 1448617

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Abstract

Corn-cob cellulose supported poly(hydroxamic acid) Cu(II) complex was prepared by the surface modification of waste corn-cob cellulose through graft copolymerization and subsequent hydroximation. The complex was characterized by IR, UV, FESEM, TEM, XPS, EDX and ICP-AES analyses. The complex has been found to be an efficient catalyst for 1,3-dipolar Huisgen cycloaddition (CuAAC) of aryl/alkyl azides with a variety of alkynes as well as one-pot three-components reaction in the presence of sodium ascorbate to give the corresponding cycloaddition products in up to 96% yield and high turn over number (TON 18,600) and turn over frequency (TOF 930 h−1) were achieved. The complex was easy to recover from the reaction mixture and reused six times without significant loss of its catalytic activity.

Item Type: Article
Uncontrolled Keywords: Cellulose; Copper; Corn-cob; Huisgen reaction; Poly(hydroxamic acid)
Subjects: Q Science > QD Chemistry
Divisions: FACULTY > Faculty of Science and Natural Resources
Depositing User: Unnamed user with email storage.bpmlib@ums.edu.my
Date Deposited: 12 Oct 2016 06:22
Last Modified: 23 Oct 2017 07:06
URI: http://eprints.ums.edu.my/id/eprint/14675

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