Fun, H.-K. and Chinnakali, K. and Sivakumar, K. and Sam, T.-W. and How, Siew Eng (1997) Substituted Methoxybenzene derivatives: C8H9NO4, C9H11NO5 and C13H18O4. Acta Crystallographica, Section C: Crystal Structure Communications. pp. 1859-1862.
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Abstract
The structures of three methoxybenzenes, namely 1,2-dimethoxy-4-nitrobenzene, C8H9NO4, (I), 1,2,3-trimethoxy-5-nitrobenzene, C9H11NO5, (II), and 1-(2,4,5-trimethoxyphenyl)-1-butanone, C13H18O4, (III), are reported. Molecules of (I) and (III) are planar, but one of the three methoxy groups of (II) is twisted out of the phenyl ring plane as a result of steric hindrance. In all three solids, the molecules are linked to form centrosymmetrically hydrogen-bonded dimers; they are packed in parallel layers in (I) and (II), but in zigzag layers in (III).
Item Type: | Article |
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Keyword: | Centrosymmetrically hydrogen-bonded dimers , methoxybenzenes |
Subjects: | Q Science > QD Chemistry |
Department: | FACULTY > Faculty of Science and Natural Resources |
Depositing User: | NORAINI LABUK - |
Date Deposited: | 28 Feb 2018 14:32 |
Last Modified: | 28 Feb 2018 14:32 |
URI: | https://eprints.ums.edu.my/id/eprint/18935 |
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