Mohd Sani Sarjadi and Tan, Shu Er and Wong, Xin Lin and Md Lutfor Rahman (2018) N-Alkylation Of 6,6’-Dibromoisoindigo via Tosylate: An Economical Pathway. ASM Science Journal., 11 (2). pp. 196-206.
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N-Alkylation Of 6,6’-Dibromoisoindigo via Tosylate An Economical Pathway.pdf Download (42kB) | Preview |
Abstract
This paper introduces a substantial and price reasonable pathway to N-alkylate the 6,6’- dibromoisoindigo. The conventional method for this N-alkylation involves the usage of alkyl bromides, which are available in the commercial with high-priced and limited amount. In this research, the price to purchase 7-(bromomethyl) pentadecane is four-fold than the cost to synthesize the relevant tosylate from 2-hexyl-1-decanol. The most suitable reaction condition to N-alkylate this 6,6’-dibromoisoindigo is by refluxing it with potassium carbonate in dried DMF under nitrogen atmosphere. After characterization, it can be concluded that 6,6’-dibromoisoindigo has been successfully N-alkylated with tosylate without involved the expensive alkyl bromide.
| Item Type: | Article |
|---|---|
| Keyword: | N-alkylation, tosylate, isoindigo, electron acceptor, conjugated polymer |
| Subjects: | Q Science > Q Science (General) T Technology > T Technology (General) |
| Department: | FACULTY > Faculty of Science and Natural Resources |
| Depositing User: | SITI AZIZAH BINTI IDRIS - |
| Date Deposited: | 14 Nov 2019 15:27 |
| Last Modified: | 14 Nov 2019 15:27 |
| URI: | https://eprints.ums.edu.my/id/eprint/24098 |
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