Improving valuable metal ions capturing from spent Li-ion batteries with novel materials and approaches

Aminul Islam and Srimonta Roy and Masud Ali Khan and Pronoy Mondal and Teo, Siow Hwa and Yap, Taufiq Yun Hin and Mohammad Tofayal Ahmed and Tasrina Rabia Choudhury and G. Abdulkreem-Alsultan and Shahjalal Khandaker and Md. Rabiul Awual (2021) Improving valuable metal ions capturing from spent Li-ion batteries with novel materials and approaches. Journal of Molecular Liquids, 338. pp. 1-14. ISSN 0167-7322 (P-ISSN) , 1873-3166 (E-ISSN)

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URL: https://www.sciencedirect.com/science/article/pii/...

Abstract

Rapid growth in the market for batteries is imperative to meet global demand. The lack of economically feasible and environmentally benign recycling process for waste batteries may cause environmental crisis. Taking effective measures could reduce the waste-management challenge and maximize the economic benefits. In this work, environmentally benign citric acid with the presence of reluctant was used to recover cobalt, manganese, nickel and lithium from waste Lithium Nickel Manganese Cobalt oxide (NCM) batteries. Recovery of Co, Mn, Ni, and Li was optimized by varying the citric acid and H2O2 concentrations, the reaction temperature and duration. The recovery of Co, Mn, Ni, and Li were 87%, 90.5%, 93.5% and 96% respectively under the optimum leaching condition of 1.2 mol/L citric acid, 10 vol% H2O2at 95 for 120 min. Interfacial reaction controlled leaching reaction at low temperature was evident from the results of leaching kinetics with apparent activation energy of 3.75, 10.405.34 and 8.72 kJ mol1 for Co, Mn, Ni and Li, respectively. Importantly, the diffusion controlled leaching reaction was evident from the kinetic and activation energy measurement of leaching. The impact of different chemicals on the environment measured from the Biwer and Heinzle Method (BHM) revealed that the citric acid-assisted leaching process to recover valuable metals from NCM batteries was appeared lower environment impact compare to the other process reported in the literature. The high leaching efficiency and lower impact to the environment provides a novel approach for metal recovery of waste NCM batteries.

Item Type:	Article
Keyword:	Batteries , Recycling , Organic solvent , Environmental impact , Leaching kinetics
Subjects:	T Technology > TK Electrical engineering. Electronics Nuclear engineering > TK1-9971 Electrical engineering. Electronics. Nuclear engineering > TK2896-2985 Production of electricity by direct energy conversion
Department:	FACULTY > Faculty of Science and Natural Resources
Depositing User:	SAFRUDIN BIN DARUN -
Date Deposited:	20 Sep 2021 14:10
Last Modified:	10 Jan 2022 15:42
URI:	https://eprints.ums.edu.my/id/eprint/30349

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