Physicochemical Properties of MoVTeNb Mixed Oxide Catalysts Synthesized using Different Vanadium Sources

Haslinda Mohd Sidek and Irmawati Ramli and Norhazlin Zainuddin and Hossein Abbastabar Ahangar and Yap, Taufiq Yun Hin (2021) Physicochemical Properties of MoVTeNb Mixed Oxide Catalysts Synthesized using Different Vanadium Sources. Sains Malaysiana, 50. pp. 2395-2405. ISSN 0126-6039

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Abstract

The use of different vanadium sources in the synthesis of multi-metal MoVTeNb oxide catalysts has been investigated for their effect on the physicochemical properties of catalysts. Metal oxides were synthesized by slurry method assisted with a microwave irradiation. Vanadium pentoxide (V2 O5), vanadyl sulphate (VOSO4) and ammonium metavanadate (NH4 VO3) were used as the vanadium sources, respectively. X-ray diffraction (XRD) pattern showed the existence of orthorhombic (M1) phases in all catalysts. The catalyst prepared using V2 O5 produced the highest formation of the phase. This was further supported by Inductive Couple Plasma-Atomic Emission Spectroscopy (ICP-AES), which showed that the V2 O5 catalyst has the highest V: Mo ratio, mainly responsible for the high catalytic activity. Temperature Programmed Reduction in Hydrogen (H2 -TPR) showed better reducibility for the catalyst when compared to the others. Temperature Programmed Reaction (TPRn) confirmed that the oxidants active for propane conversion into acrylic acid were originated from the lattice of the catalyst.

Item Type:	Article
Keyword:	Acrylic acid , Anaerobic reaction , MoVTeNb mixed metal oxide , Ropane oxidation , Vanadium source
Subjects:	Q Science > Q Science (General) > Q1-390 Science (General)
Department:	FACULTY > Faculty of Science and Natural Resources
Depositing User:	SITI AZIZAH BINTI IDRIS -
Date Deposited:	30 Mar 2022 10:48
Last Modified:	30 Mar 2022 10:48
URI:	https://eprints.ums.edu.my/id/eprint/32095

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