Preliminary study of reduced graphene oxide-titanium (rGO-TiO₂) photocatalyst for CO₂ reduction into methane: the physicochemical analysis & photocatalyst performance

Huzaikha Awang and Tan, Lling Lling (2021) Preliminary study of reduced graphene oxide-titanium (rGO-TiO₂) photocatalyst for CO₂ reduction into methane: the physicochemical analysis & photocatalyst performance.

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Abstract

The two major global issues; climate change and global energy demand will have been increasing in the future especially in both developing and developed countries. These two major global issues are basically due to the industrial activity and advanced lifestyle in that country. Therefore, the Carbon Capture and Conversion (CCC) method had been used in this research work. The CCC method has been used to capture and convert the CO₂ gas into hydrocarbon fuels such as methane gas. The Reduced graphene oxide-Titanium (rGO-TiO₂) sample in this experiment has been used to evaluate two research questions: the effect of synthesis method in sample’s physicochemical properties and the photocatalytic performance. There are three synthesize methods had used to extract the samples; solvothermal method by using a Tetrabutyl Titanate powder (TBT) as raw material, hydrothermal method by using TBT as raw material and hydrothermal method by using anatase P90 TiO₂ powder as a raw material. These three samples were fused at fixed temperature and treatment time with 180oC and 8 hours, respectively. The physicochemical properties of these three samples had been characterized via X-ray Diffractometry (XRD) and UV-Vis spectrophotometer. Furthermore, the Gas Chromatograph (GC) was used to examine the photocatalytic performance at the end of this experiment. The rGO-TiO₂ (H1) sample shows the best photocatalytic performance with 700 nmol/gcat number of methane (CH4) yield within 8 hours which obviously higher than rGO-TiO2 (S) and rGO-Anatase TiO₂ (H2) with only 387 nmol/ gcat and 297 nmol/gcat respectively. It can be concluded that the synthesis method had been affecting the physicochemical properties and the photocatalytic performance in photocatalysts.

Item Type: Proceedings
Keyword: Titanium dioxide, Graphene, Reduced Graphene, Photocatalyst, Photocatalytic
Subjects: Q Science > Q Science (General) > Q1-390 Science (General)
T Technology > TN Mining engineering. Metallurgy > TN1-997 Mining engineering. Metallurgy
Department: CENTRE > Preparation Centre for Science and Technology
Depositing User: SITI AZIZAH BINTI IDRIS -
Date Deposited: 25 Oct 2024 09:29
Last Modified: 25 Oct 2024 09:29
URI: https://eprints.ums.edu.my/id/eprint/41618

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