A recyclable silica gel-supported schiff-base palladium nanocatalyst for suzuki-miyaura coupling and green organic synthesis

Shaheen M. Sarkar and Md Lutfor Rahman and Kamrul Hasan and Md. Maksudur Rahman Khan and Mohammed Salim Akhter and Emmet J. OReilly (2025) A recyclable silica gel-supported schiff-base palladium nanocatalyst for suzuki-miyaura coupling and green organic synthesis. Inorganic Chemistry Communications, 179. pp. 1-16. ISSN 1387-7003

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Abstract

We developed a cost-effective silica gel-supported Schiff-base palladium nanocatalyst (Si@SBPdNPs 3) using a novel three-step synthesis. First, silica gel was functionalized with an aminosilane compound, followed by Schiff base formation through reaction with 1,10-phenanthroline-2,9-dicarboxaldehyde. Palladium nanoparticles were then introduced using hydrazine hydrate as the reducing agent. FT-IR and XRD confirmed successful functionalization, while SEM images revealed spherical silica particles averaging 50 µm in diameter. TEM analysis showed well-dispersed palladium nanoparticles with an average size of 5.93 ± 0.1 nm. ICP and EDX data indicated a palladium loading of 0.023 mol%, and XPS analysis confirmed the presence of Pd(0) coordinated with the Schiff base ligand. The nanocatalyst demonstrated outstanding activity in Suzuki-Miyaura cross-coupling reactions under mild conditions, efficiently coupling various aryl halides with organoboronic acids to afford high product yields. It also proved effective in synthesizing the biologically active fungicide Boscalide. Moreover, the catalyst could be recovered and reused up to six times with minimal loss of activity, underscoring its sustainability and environmental compatibility. This robust, recyclable nanocatalyst offers a promising, scalable approach for C–C bond formation, with broad potential for applications in green and economical organic synthesis.

Item Type:	Article
Keyword:	Aryl halides, Organoboronic acid, Schiff base, Silica gel, Palladium nanocatalyst, Suzuki reaction
Subjects:	Q Science > QD Chemistry > QD1-999 Chemistry > QD241-441 Organic chemistry T Technology > TP Chemical technology > TP1-1185 Chemical technology > TP155-156 Chemical engineering
Department:	FACULTY > Faculty of Science and Technology
Depositing User:	SITI AZIZAH BINTI IDRIS -
Date Deposited:	15 Jul 2025 15:36
Last Modified:	15 Jul 2025 15:36
URI:	https://eprints.ums.edu.my/id/eprint/44465

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